The chemistry of MIL-125 based materials: Structure, synthesis ...
2022年2月1日 · MIL-125 is a Ti-based MOF derived from Ti metal ions and carboxylate organic ligands. Different modification strategies have been outlined, such as functionalizing with ligands, modifying with metal ions, or incorporating other materials.
The chemistry of MIL-125 based materials: Structure, synthesis ...
2022年2月1日 · MIL-125 is a Ti-based MOF derived from Ti metal ions and carboxylate organic ligands. Different modification strategies have been outlined, such as functionalizing with ligands, modifying with metal ions, or incorporating other materials.
Adsorption/catalytic properties of MIL-125 and NH2-MIL-125
2013年4月15日 · A Ti-incorporated metal organic framework structure, MIL-125, and its amine-functionalized form, NH 2 -MIL-125, were synthesized via a solvothermal route aided by microwave heating. The samples were characterized by XRD, SEM, TGA, EA, UV–vis spectroscopy, and N 2 adsorption–desorption measurements.
Engineering the Optical Response of the Titanium-MIL-125 …
2013年7月10日 · Herein we discuss band gap modification of MIL-125, a TiO 2 /1,4-benzenedicarboxylate (bdc) metal–organic framework (MOF). Through a combination of synthesis and computation, we elucidated the electronic structure of MIL-125 with aminated linkers.
A New Photoactive Crystalline Highly Porous Titanium(IV) …
2009年7月21日 · We present here MIL-125, the first example of a highly porous and crystalline titanium (IV) dicarboxylate (MIL stands for Materials of Institut Lavoisier) with a high thermal stability and photochemical properties.
Trace benzene capture by decoration of structural defects in metal ...
2024年10月29日 · Here we report the adsorption of trace benzene by decorating a structural defect in MIL-125-defect with single-atom metal centres to afford MIL-125-X (X = Mn, Fe, Co, Ni, Cu, Zn; MIL-125, Ti...
Gram-scale synthesis of MIL-125 nanoparticles and their solution ...
2023年8月7日 · Here, we report a rapid reflux-based synthesis of MIL-125 nanoparticles to access sizes below 30 nm with indefinite colloidal stability and BET surface areas exceeding that of the bulk, stemming from the higher surface-to-volume ratio …
MIL-125-based nanocarrier decorated with Palladium complex for …
2022年7月15日 · Hence, the porous ultra-low-density materials, metal–organic frameworks (MOFs), have been considered and the MIL-125 (Ti) has been chosen due to its distinctive characteristics such as great...
MIL-125 (Ti)@ZIF-67-derived MIL-125 (Ti)@TiO2 hollow …
2023年6月26日 · Here, a two-step synthetic strategy was designed to prepare MIL-125 (Ti)@TiO 2 hollow nanodiscs decorated with Co 3 S 4 nanoparticles for CO 2 photoreduction. The Co-based zeolite imidazolium ester backbone (ZIF-67) nanolayer was first loaded on the prepared MIL-125 (Ti) nanodiscs to form core@shell MIL-125 (Ti)@ZIF-67 nanodiscs.
MIL-125-NH2@TiO2 Core–Shell Particles Produced by a Post …
2018年4月25日 · The MIL-125-NH 2 @TiO 2 core–shell particles combine the advantages of highly active TiO 2 nanosheets, MIL-125-NH 2 photosensitizer, plenty of linker defects and oxygen vacancies, and mesoporous structure, which allows them to be utilized as photocatalysts for the visible-light-driven hydrogen production reaction.
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